Thursday, June 27, 2013

Thiosulfate, an excellent fluid sulfur source

Thiosulfate (S2O32-) fertilizers are clear liquids that provide a source of sulfur (S) and can be used in a variety of situa­tions. They also contain other nutrients including nitrogen (N) as ammonium (ATS), potassium (KTS), calcium (CaTS), or magnesium (MgTS).

 
Thiosulfate fertilizer
 Production
ATS is the most commonly used S-containing fluid fertilizer. It is made by reaction of sulfur dioxide, elemental S, and aque­ous ammonia. Other common fluid thiosulfate fertilizers are similarly produced.


Thiosulfates are highly soluble in water and are compatible with many other fluid fertilizers. ATS is commonly mixed with urea ammonium nitrate (UAN) to produce a widely used fertilizer with the analysis 28-0-0-5 (5% S).

Chemical Properties
Formula Common             Nutrient                Density,               pH
name                              content                     kg/L                                        

(NH4)2S2O3 ATS         12% N; 26% S           1.34                  7 to 8.5
K2S2O3        KTS         25% K2O; 17% S       1.46                7.5 to 8
CaS2O3       CaTS          6% Ca; 10% S          1.25                6.5 to 8
MgS2O3      MgTS          4% Mg; 10% S          1.23               6.5 to 7.5

Agricultural Use
After application to soil, most of the thiosulfate quickly reacts to form tetrathionate, which is subsequently converted to sulfate. Thiosulfate is not generally available for plant uptake until it is converted to sulfate. In warm soils, this process is largely complete within one to two weeks.
Molecular structure of
thiosulfate and tetrathionate

Thiosulfate is a chemical “reducing agent” and it also produces acidity after oxidation of the S. Due to these properties, thio­sulfate molecules have unique effects on soil chemistry and biology. For example, a band application of ATS has been shown to improve the solubility of some micronutrients. Local guidelines should be followed for maximum rates for placement in the seed row.

Thiosulfate can slow the rate of urea hydrolysis…the conversion of urea to ammonium (NH4+)…and reduce loss of ammonia (NH3) as a gas when ATS is mixed with UAN. This inhibiting effect is likely due to the formation and presence of the intermedi­ate tetrathionate, rather than the thiosulfate itself. Nitrification...the conversion of NH4+ to nitrate...is also slowed in the presence of ATS. Although the initial pH of thiosulfate fertilizers is near neutral, thiosulfate oxidizes to form sulfuric acid and the NH4+ in ATS will form nitric acid, thus resulting in slight soil acidification in the application zone.
Sulfur-deficient corn

Thiosulfates may be applied through surface and overhead irrigation systems, sprinklers, and drip irrigation. Many of them are used in foliar sprays to provide a rapid source of plant nutrition (not recommended with ATS).

Management Practices
Sulfur deficiencies are noted in crops throughout the world. Thiosulfates are valuable fertilizer materials because they are easy to handle and apply, require minimal safety precautions, and are compatible with many other common fertilizers. However, these fertilizers should not be mixed with highly acidic solutions since this will cause the decomposition of the thiosulfate molecule and subsequent release of harmful sulfur dioxide gas.


Non-Agricultural Use
Thiosulfate materials are used in a variety of industrial applications. In photographic processing, they are used to bind silver atoms present in film or paper. Sodium thiosulfate is used in water treatment systems to remove chlorine. It is also used for gold extraction, since it forms a strong complex with this metal in a non-toxic process.


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